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https://hdl.handle.net/2440/56562
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dc.contributor.author | Hollis, C. | - |
dc.contributor.author | Hanton, L. | - |
dc.contributor.author | Morris, J. | - |
dc.contributor.author | Sumby, C. | - |
dc.date.issued | 2009 | - |
dc.identifier.citation | Crystal Growth and Design, 2009; 9(6):2911-2916 | - |
dc.identifier.issn | 1528-7483 | - |
dc.identifier.issn | 1528-7505 | - |
dc.identifier.uri | http://hdl.handle.net/2440/56562 | - |
dc.description.abstract | As part of our studies of ligands containing an electron-deficient [3]-radialene core we discovered that the hexadentate ligand hexa(4-cyanophenyl)[3]-radialene 1 forms 6,3-connected 2-D coordination polymers on reaction with silver(I). Compounds {[Ag(1)](PF6) · 2(CH3NO2)}n 2 and {[Ag(1)](ClO4) · 2(CH3NO2)}n 3, which are the first coordination polymers of 1, readily crystallize from solutions of the silver salt and 1 in noncoordinating nitromethane solvent and were characterized by X-ray crystallography. In these structures the ligand is hypodentate, coordinating only through four nitrile N-donors to act as a 3-connecting center. The distorted tetrahedral silver also acts as a 3-connecting center. In the extended structure the anions lie in pockets above and below the [3]-radialene core of the ligands, forming moderate and weak hydrogen bonds with four different molecules of 1. The anions are in close proximity to the electron-deficient [3]-radialene core of 1, forming weak anion-π interactions. | - |
dc.description.statementofresponsibility | Courtney A. Hollis, Lyall R. Hanton, Jonathan C. Morris, and Christopher J. Sumby | - |
dc.language.iso | en | - |
dc.publisher | American Chemical Society | - |
dc.rights | © 2009 American Chemical Society | - |
dc.source.uri | http://dx.doi.org/10.1021/cg9002302 | - |
dc.title | 2-D Coordination Polymers of Hexa(4-cyanophenyl)[3]-radialene and Silver(I): Anion•••π-Interactions and Radialene C−H•••Anion Hydrogen Bonds in the Solid-State Interactions of Hexaaryl[3]-radialenes with Anions | - |
dc.title.alternative | 2-D Coordination Polymers of Hexa(4-cyanophenyl)[3]-radialene and Silver(I): Anion (.)(.)(.) pi-Interactions and Radialene C-H(.)(.)(.)Anion Hydrogen Bonds in the Solid-State Interactions of Hexaaryl[3]-radialenes with Anions | - |
dc.type | Journal article | - |
dc.identifier.doi | 10.1021/cg9002302 | - |
dc.relation.grant | ARC | - |
pubs.publication-status | Published | - |
dc.identifier.orcid | Sumby, C. [0000-0002-9713-9599] | - |
Appears in Collections: | Aurora harvest Chemistry publications Environment Institute publications |
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