Adelaide Research & Scholarship
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https://hdl.handle.net/2440/853
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| Type: | Journal article |
| Title: | Comparison of singlet methylene removal rates by Group IV Hydrides |
| Author: | Gutsche, G. Staker, W. King, K. |
| Citation: | International Journal of Chemical Kinetics, 1995; 27(6):623-626 |
| Publisher: | Wiley & Sons |
| Issue Date: | 1995 |
| ISSN: | 0538-8066 1097-4601 |
| Abstract: | <jats:title>Abstract</jats:title><jats:p>The technique of laser flash photolysis/laser absorption has been used to obtain an absolute removal rate constant of (3.85 ± 0.18) × 10<jats:sup>−10</jats:sup> cm<jats:sup>3</jats:sup> molecule<jats:sup>−1</jats:sup> s<jats:sup>−1</jats:sup> for singlet methylene, <jats:sup>1</jats:sup>CH<jats:sub>2</jats:sub> (ã<jats:sup>1</jats:sup>A<jats:sub>1</jats:sub>), with germane (GeH<jats:sub>4</jats:sub>) at ambient temperature. The removal rate constant is compared with the values for methane (CH<jats:sub>4</jats:sub>) and silane (SiH<jats:sub>4</jats:sub>) which have been determined previously. © 1995 John Wiley & Sons, Inc.</jats:p> |
| DOI: | 10.1002/kin.550270612 |
| Published version: | http://dx.doi.org/10.1002/kin.550270612 |
| Appears in Collections: | Aurora harvest 6 Chemical Engineering publications |
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