Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/55668
Citations | ||
Scopus | Web of ScienceĀ® | Altmetric |
---|---|---|
?
|
?
|
Type: | Journal article |
Title: | Laser photoelectron spectroscopy and dynamics of S1 p-fluorotoluene |
Author: | Bellm, S. Whiteside, P. Reid, K. |
Citation: | The Journal of Physical Chemistry A: Isolated Molecules, Clusters, Radicals, and Ions; Environmental Chemistry, Geochemistry, and Astrochemistry; Theory, 2003; 107(38):7373-7379 |
Publisher: | Amer Chemical Soc |
Issue Date: | 2003 |
ISSN: | 1089-5639 1520-5215 |
Statement of Responsibility: | Susan M. Bellm, Paul T. Whiteside, and Katharine L. Reid |
Abstract: | Laser photoelectron spectra have been obtained following the preparation of 10 vibrational states in S1 p-fluorotoluene. For eight of the vibrational states (up to 850 cm-1 excess energy), excitation and ionization with nanosecond laser pulses gives rise to photoelectron spectra with well-resolved vibrational peaks. For the other two states (>1100 cm-1 excess energy), the photoelectron spectra show a loss of structure when nanosecond pulses are used, as a result of intramolecular dynamics, but this structure is recovered when overlapped picosecond pulses are used. In all cases the vibrational peaks in the photoelectron spectra are assigned, and the spectra are used to deduce the frequencies of 12 vibrational modes in the ion. |
DOI: | 10.1021/jp030341 |
Published version: | http://dx.doi.org/10.1021/jp030341+ |
Appears in Collections: | Aurora harvest 5 Chemistry publications |
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.