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Type: Journal article
Title: Synthesis and preliminary analytical evaluation of the chemiluminescence from (4-[4-(dichloromethylsilanyl)-butyl]-4'-methyl-2 2'-bipyridyl)bis(2 2'-bipyridyl))ruthenium(II) covalently bonded to silica particles
Author: Barnett, N.
Bos, R.
Brand, H.
Jones, P.
Lim, K.
Purcell, S.
Russell, R.
Citation: Analyst, 2002; 127(4):455-458
Publisher: Royal Soc Chemistry
Issue Date: 2002
ISSN: 0003-2654
Statement of
Neil W. Barnett, Richard Bos, Holger Brand, Philip Jones, Kieran F. Lim, Stuart D. Purcell and Richard A. Russell
Abstract: This paper describes, for the first time, a simple and effective synthetic route for covalently bonding the chemiluminescence reagent, (4-[4-(dichloromethylsilanyl)-butyl]-4-methyl-2,2-bipyridyl)bis(2,2-bipyridyl)ruthenium(II) onto silica particles. The subsequent preparation of chemically regeneratable detection cells and their preliminary analytical evaluation with both sequential injection analysis and flow injection analysis are also reported. Unoptimised analytical figures of merit were established for standard solutions of codeine and sodium oxalate with detection limits calculated from three times the standard deviation of the blank signal, of 1 × 10–8 M and 3 × 10–7 M respectively. The chemically immobilised reagent exhibited some intriguing solvent and kinetic effects, which are also briefly discussed.
Description: Copyright © 2002 Royal Society of Chemistry
RMID: 0020082803
DOI: 10.1039/b200794k
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Appears in Collections:Adelaide Graduate Centre publications

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