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dc.contributor.authorBarnett, N.en
dc.contributor.authorBos, R.en
dc.contributor.authorBrand, H.en
dc.contributor.authorJones, P.en
dc.contributor.authorLim, K.en
dc.contributor.authorPurcell, S.en
dc.contributor.authorRussell, R.en
dc.identifier.citationAnalyst, 2002; 127(4):455-458en
dc.descriptionCopyright © 2002 Royal Society of Chemistryen
dc.description.abstractThis paper describes, for the first time, a simple and effective synthetic route for covalently bonding the chemiluminescence reagent, (4-[4-(dichloromethylsilanyl)-butyl]-4-methyl-2,2-bipyridyl)bis(2,2-bipyridyl)ruthenium(II) onto silica particles. The subsequent preparation of chemically regeneratable detection cells and their preliminary analytical evaluation with both sequential injection analysis and flow injection analysis are also reported. Unoptimised analytical figures of merit were established for standard solutions of codeine and sodium oxalate with detection limits calculated from three times the standard deviation of the blank signal, of 1 × 10–8 M and 3 × 10–7 M respectively. The chemically immobilised reagent exhibited some intriguing solvent and kinetic effects, which are also briefly discussed.en
dc.description.statementofresponsibilityNeil W. Barnett, Richard Bos, Holger Brand, Philip Jones, Kieran F. Lim, Stuart D. Purcell and Richard A. Russellen
dc.publisherRoyal Soc Chemistryen
dc.titleSynthesis and preliminary analytical evaluation of the chemiluminescence from (4-[4-(dichloromethylsilanyl)-butyl]-4'-methyl-2 2'-bipyridyl)bis(2 2'-bipyridyl))ruthenium(II) covalently bonded to silica particlesen
dc.typeJournal articleen
pubs.library.collectionAdelaide Graduate Centre publicationsen
Appears in Collections:Adelaide Graduate Centre publications

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