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https://hdl.handle.net/2440/47084
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DC Field | Value | Language |
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dc.contributor.author | Xia, F. | - |
dc.contributor.author | Zhou, J. | - |
dc.contributor.author | Brugger, J. | - |
dc.contributor.author | Ngothai, Y. | - |
dc.contributor.author | O'Neill, B. | - |
dc.contributor.author | Chen, G. | - |
dc.contributor.author | Pring, A. | - |
dc.date.issued | 2008 | - |
dc.identifier.citation | Chemistry of Materials, 2008; 20(8):2809-2817 | - |
dc.identifier.issn | 0897-4756 | - |
dc.identifier.issn | 1520-5002 | - |
dc.identifier.uri | http://hdl.handle.net/2440/47084 | - |
dc.description.abstract | A novel route for the synthesis of complex metal sulfides using hydrothermal coupled dissolutionreprecipitation reactions is reported. Two thiospinels, (Ni,Fe)₃S₄ (violarite) and Co₃S₄ (linnaeite), were synthesized using (Fe,Ni)₉S₈ (pentlandite) and Co₉S₈ (cobaltpentlandite) as precursors. The Fe/Ni ratio of (Ni,Fe)₃S₄ can be adjusted by varying the reaction conditions, for example, temperature (125–145 °C), pH (2.90, 3.90, 5.00), and precursor stoichiometry ((FexNi1-x)₉S₈, x = 0.4, 0.5, 0.55, 0.6). Pure (Ni,Fe)₃S₄ can be synthesized by utilizing a flow-through hydrothermal cell rather than a static hydrothermal cell as the fluid flow improves mass transfer and flushes away the Fe₂O₃ byproduct from the reaction front. Synthesis times range from 10 to 20 days, compared to the traditional dry synthesis route for (Ni,Fe)₃S₄ that requires 3 months annealing to obtain a product of only 72 ± 3 wt % purity. This synthesis route is ideal for preparing compounds with low thermal stabilities (<500 °C). | - |
dc.language.iso | en | - |
dc.publisher | Amer Chemical Soc | - |
dc.source.uri | http://dx.doi.org/10.1021/cm7033883 | - |
dc.title | Novel route to synthesize complex metal sulfides: Hydrothermal coupled dissolution-reprecipitation replacement reactions | - |
dc.type | Journal article | - |
dc.identifier.doi | 10.1021/cm7033883 | - |
pubs.publication-status | Published | - |
dc.identifier.orcid | Ngothai, Y. [0000-0002-0199-4225] | - |
Appears in Collections: | Aurora harvest 6 Chemical Engineering publications |
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