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https://hdl.handle.net/2440/137056
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dc.contributor.author | Smedley, C.J. | - |
dc.contributor.author | Giel, M.C. | - |
dc.contributor.author | Molino, A. | - |
dc.contributor.author | Barrow, A.S. | - |
dc.contributor.author | Wilson, D.J.D. | - |
dc.contributor.author | Moses, J.E. | - |
dc.date.issued | 2018 | - |
dc.identifier.citation | Chemical Communications, 2018; 54(47):6020-6023 | - |
dc.identifier.issn | 1359-7345 | - |
dc.identifier.issn | 1364-548X | - |
dc.identifier.uri | https://hdl.handle.net/2440/137056 | - |
dc.description.abstract | We demonstrate 1,2-dibromoethane-1-sulfonyl fluoride (DESF) as a bench-stable and readily accessible precursor to the robust SuFEx connector, 1-bromoethene-1-sulfonyl fluoride (BESF). The in situ generation of BESF from DESF opens up several new reaction profiles, including application in the syntheses of unprecedented 3-substituted isoxazole-5-sulfonyl fluorides, 1-substituted-1H1,2,3-triazole-4-sulfonyl fluorides, 2-amino-1-bromoethane-1-sulfonyl fluorides and 4-bromo-b-sultams in good to excellent yields. These new modules comprise a pendant sulfonyl fluoride handle, which further undergoes facile and selective SuFEx reactions with a selection of aryl silyl ethers to generate stable and useful sulfonate connections. | - |
dc.description.statementofresponsibility | Christopher J. Smedley, Marie-Claire Giel, Andrew Molino, Andrew S. Barrow, David J. D. Wilson and John E. Moses | - |
dc.language.iso | en | - |
dc.publisher | Royal Society of Chemistry (RSC) | - |
dc.rights | © The Royal Society of Chemistry 2018 | - |
dc.source.uri | http://dx.doi.org/10.1039/c8cc03400a | - |
dc.title | 1-Bromoethene-1-sulfonyl fluoride (BESF) is another good connective hub for SuFEx click chemistry | - |
dc.type | Journal article | - |
dc.identifier.doi | 10.1039/c8cc03400a | - |
dc.relation.grant | http://purl.org/au-research/grants/arc/FT170100156 | - |
pubs.publication-status | Published | - |
dc.identifier.orcid | Barrow, A.S. [0000-0003-3661-5173] | - |
Appears in Collections: | Chemistry publications |
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