Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/136835
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Type: | Journal article |
Title: | The Dynamic Formation from Metal-Organic Frameworks of High-Density Pt Single Atom Catalysts with Metal-Metal Interactions |
Author: | Shan, J. Liao, J. Ye, C. Dong, J. Zheng, Y. Qiao, S. |
Citation: | Angewandte Chemie International Edition, 2022; 61(48):e202213412-1-e202213412-10 |
Publisher: | Wiley-VCH GmbH |
Issue Date: | 2022 |
ISSN: | 1433-7851 1521-3773 |
Statement of Responsibility: | Jieqiong Shan, Jiangwen Liao, Chao Ye, Juncai Dong, Yao Zheng, and Shi-Zhang Qiao |
Abstract: | Single atom catalysts (SACs) hold great promise for highly efficient heterogeneous catalysis, yet the practical applications require the development of high-density active sites with flexible geometric structures. The lack of understanding in the dynamic formation process of single atoms in the host framework has been plaguing the controllable synthesis of next generation SACs. Here using Co-based metal-organic frameworks as a starting substrate, we fully elucidated the formation of high-density Pt single atoms with inter-site interactions in derived Co 3 O 4 host. The cation exchange process and dynamic evolution of Pt-Pt interactions, organic ligand cleavage and Pt-oxygen coordination formation during the pyrolysis process have been unambiguously interpreted by a series of in-situ/ex-situ spectroscopic measurements and theoretical computation. These findings would direct the synthesis of high-density SACs with metal-metal interactions, which demonstrate significantly enhanced structural flexibility and catalytic properties. |
Keywords: | hard-soft acid-base principle metal-metal interactions metal-organic frameworks pyrolysis single atom catalysts |
Description: | Version of record online: October 27, 2022 |
Rights: | © 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. |
DOI: | 10.1002/anie.202213412 |
Grant ID: | http://purl.org/au-research/grants/arc/FL170100154 http://purl.org/au-research/grants/arc/DP220102596 http://purl.org/au-research/grants/arc/FT200100062 http://purl.org/au-research/grants/arc/DP190103472 |
Published version: | http://dx.doi.org/10.1002/anie.202213412 |
Appears in Collections: | Chemical Engineering publications |
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hdl_136835.pdf | Published version | 2.97 MB | Adobe PDF | View/Open |
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