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https://hdl.handle.net/2440/134549
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Type: | Journal article |
Title: | A 3D multifunctional architecture for lithium–sulfur batteries with high areal capacity |
Author: | Zhao, S. Fang, R. Sun, Z. Wang, S. Veder, J. Saunders, M. Cheng, H. Liu, C. Jiang, S.P. Li, F. |
Citation: | Small Methods, 2018; 2(6):1800067-1-1800067-9 |
Publisher: | Wiley |
Issue Date: | 2018 |
ISSN: | 2366-9608 2366-9608 |
Statement of Responsibility: | Shiyong Zhao, Ruopian Fang, Zhenhua Sun, Shaogang Wang, Jean-Pierre Veder, Martin Saunders, Hui-Ming Cheng, Chang Liu, San Ping Jiang, and Feng Li |
Abstract: | Lithium–sulfur (Li–S) batteries are highly attractive as next-generation electrochemical energy-storage technologies because they can provide a high energy density at a low cost. However, the performance degradation of sulfur cathodes with high mass loadings remains a significant challenge to be addressed. Here, a 3D multifunctional integrated and sponge-like architecture is designed as the cathode framework, which provides a favorable balance between high sulfur loadings and uncompromised electrochemical performances. In this architecture, a highly porous nitrogen-doped carbon fiber foam is used as a 3D current collector and host for sulfur accommodation and a thin graphene layer is used for polysulfide interception, which not only facilitates fast electron and lithium-ion transport but also enables effective active material immobilization by both physical restriction and chemical adsorption. With a sulfur loading of 7.7 mg cm⁻², high areal capacities up to 8.7 mAh cm⁻² are attained together with excellent cycling stability over 500 cycles. This approach demonstrates a new concept for the construction of cathode architectures for practical Li–S batteries and can be extended to other battery systems. |
Keywords: | High energy density; high sulfur loading; lithium–sulfur batteries |
Rights: | © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
DOI: | 10.1002/smtd.201800067 |
Grant ID: | http://purl.org/au-research/grants/arc/DP150102044 http://purl.org/au-research/grants/arc/DP150102025 http://purl.org/au-research/grants/arc/DP180100731 |
Published version: | http://dx.doi.org/10.1002/smtd.201800067 |
Appears in Collections: | Chemical Engineering publications |
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