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https://hdl.handle.net/2440/121976
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Type: | Journal article |
Title: | Nanostructured molybdenum nitride-based coatings: effect of nitrogen concentration on microstructure and mechanical properties |
Author: | Wang, J. Munroe, P. Zhou, Z. Xie, Z. |
Citation: | Thin Solid Films, 2019; 682:82-92 |
Publisher: | Elsevier |
Issue Date: | 2019 |
ISSN: | 0040-6090 |
Statement of Responsibility: | Jian Wang, Paul Munroe, Zhifeng Zhou, Zonghan Xie |
Abstract: | Molybdenum nitride (MoNₓ) coatings were deposited onto AISI M2 tool steel substrates (hardened to HRC 60) by magnetron sputtering. The nitrogen content was controlled by means of a closed-loop optical emission monitor. The coating microstructure was examined by X-ray photoelectron spectroscopy, X-ray diffraction, scanning electron microscopy and transmission electron microscopy. This showed that the increased nitrogen content led to a transformation from body-centered cubic α-Mo phase to γ-Mo₂N phase (NaCl-B1 type) and then to a face-centered cubic MoN phase. The mechanical and tribological properties of these coatings were evaluated by nano-indentation, wear and scratch testing. The γ-Mo₂N coating showed the highest hardness and the highest values of H (hardness)/E* (effective elastic modulus) and H³/E* ratio. During scratch and wear tests, the γ-Mo₂N coating exhibited the best resistance to deformation and the lowest wear rate. |
Keywords: | Molybdenum nitride coatings; magnetron sputtering; optical emission monitoring; wear tests; scratch tests |
Rights: | © 2019 Published by Elsevier B.V. |
DOI: | 10.1016/j.tsf.2019.05.011 |
Grant ID: | http://purl.org/au-research/grants/arc/DP150102417 |
Published version: | http://dx.doi.org/10.1016/j.tsf.2019.05.011 |
Appears in Collections: | Aurora harvest 4 Mechanical Engineering publications |
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