Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/120902
Citations | ||
Scopus | Web of Science® | Altmetric |
---|---|---|
?
|
?
|
Type: | Journal article |
Title: | Metal-organic framework (MOF) derived electrodes with robust and fast lithium storage for Li-ion hybrid capacitors |
Author: | Dubal, D. Jayaramulu, K. Sunil, J. Kment, Š. Gomez-Romero, P. Narayana, C. Zbořil, R. Fischer, R. |
Citation: | Advanced Functional Materials, 2019; 29(19):1900532-1-1900532-11 |
Publisher: | Wiley |
Issue Date: | 2019 |
ISSN: | 1616-301X 1616-3028 |
Statement of Responsibility: | Deepak P. Dubal, Kolleboyina Jayaramulu, Janaky Sunil, Štěpán Kment, Pedro Gomez-Romero, Chandrabhas Narayana, Radek Zbořil and Roland A. Fischer |
Abstract: | Hybrid metal–organic frameworks (MOFs) demonstrate great promise as ideal electrode materials for energy‐related applications. Herein, a well‐organized interleaved composite of graphene‐like nanosheets embedded with MnO₂ nanoparticles (MnO₂@C‐NS) using a manganese‐based MOF and employed as a promising anode material for Li‐ion hybrid capacitor (LIHC) is engineered. This unique hybrid architecture shows intriguing electrochemical properties including high reversible specific capacity 1054 mAh g⁻¹ (close to the theoretical capacity of MnO₂, 1232 mAh g⁻¹) at 0.1 A g⁻¹ with remarkable rate capability and cyclic stability (90% over 1000 cycles). Such a remarkable performance may be assigned to the hierarchical porous ultrathin carbon nanosheets and tightly attached MnO₂ nanoparticles, which provide structural stability and low contact resistance during repetitive lithiation/delithiation processes. Moreover, a novel LIHC is assembled using a MnO₂@C‐NS anode and MOF derived ultrathin nanoporous carbon nanosheets (derived from other potassium‐based MOFs) cathode materials. The LIHC full‐cell delivers an ultrahigh specific energy of 166 Wh kg⁻¹ at 550 W kg⁻¹ and maintained to 49.2 Wh kg⁻¹ even at high specific power of 3.5 kW kg⁻¹ as well as long cycling stability (91% over 5000 cycles). This work opens new opportunities for designing advanced MOF derived electrodes for next‐generation energy storage devices. |
Keywords: | Energy density; energy storage; Li-ion capacitors; manganese oxide; MOF-derived materials; nanoporous carbon |
Rights: | © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
DOI: | 10.1002/adfm.201900532 |
Grant ID: | http://purl.org/au-research/grants/arc/FT180100058 |
Published version: | http://dx.doi.org/10.1002/adfm.201900532 |
Appears in Collections: | Aurora harvest 4 Chemical Engineering publications |
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.