Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/117060
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dc.contributor.author | Zhang, W. | - |
dc.contributor.author | Jiang, X. | - |
dc.contributor.author | Zhao, Y. | - |
dc.contributor.author | Carné-Sánchez, A. | - |
dc.contributor.author | Malgras, V. | - |
dc.contributor.author | Kim, J. | - |
dc.contributor.author | Kim, J. | - |
dc.contributor.author | Wang, S. | - |
dc.contributor.author | Liu, J. | - |
dc.contributor.author | Jiang, J. | - |
dc.contributor.author | Yamauchi, Y. | - |
dc.contributor.author | Hu, M. | - |
dc.date.issued | 2017 | - |
dc.identifier.citation | Chemical Science, 2017; 8(5):3538-3546 | - |
dc.identifier.issn | 2041-6520 | - |
dc.identifier.issn | 2041-6539 | - |
dc.identifier.uri | http://hdl.handle.net/2440/117060 | - |
dc.description.abstract | While bulk-sized metal-organic frameworks (MOFs) face limits to their utilization in various research fields such as energy storage applications, nanoarchitectonics is believed to be a possible solution. It is highly challenging to realize MOF nanobubbles with monocrystalline frameworks. By a spatially controlled etching approach, here, we can achieve the synthesis of zeolitic imidazolate framework (ZIF-8) nanobubbles with a uniform size of less than 100 nm. Interestingly, the ZIF-8 nanobubbles possess a monocrystalline nanoshell with a thickness of around 10 nm. Under optimal pyrolytic conditions, the ZIF-8 nanobubbles can be converted into hollow carbon nanobubbles while keeping their original shapes. The structure of the nanobubble enhances the fast Na⁺/K⁺ ion intercalation performance. Such remarkable improvement cannot be realized by conventional MOFs or their derived carbons. | - |
dc.description.statementofresponsibility | Wei Zhang, Xiangfen Jiang, Yanyi Zhao, Arnau Carné-Sánchez, Victor Malgras, Jeonghun Kim, Jung Ho Kim, Shaobin Wang, Jian Liu, Ji-Sen Jiang, Yusuke Yamauchi and Ming Hu | - |
dc.language.iso | en | - |
dc.publisher | Royal Society of Chemistry | - |
dc.rights | This journal is © The Royal Society of Chemistry 2017 This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. | - |
dc.source.uri | http://dx.doi.org/10.1039/c6sc04903f | - |
dc.title | Hollow carbon nanobubbles: monocrystalline MOF nanobubbles and their pyrolysis | - |
dc.type | Journal article | - |
dc.identifier.doi | 10.1039/c6sc04903f | - |
pubs.publication-status | Published | - |
dc.identifier.orcid | Wang, S. [0000-0002-1751-9162] | - |
Appears in Collections: | Aurora harvest 3 Chemical Engineering publications |
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File | Description | Size | Format | |
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hdl_117060.pdf | Published version | 1.58 MB | Adobe PDF | View/Open |
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