Adelaide Research & Scholarship
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https://hdl.handle.net/2440/86625
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| Type: | Journal article |
| Title: | Mechanism of acetal cleavage with methylmagnesium iodide |
| Author: | Abell, A.D. Massywestropp, R.A. |
| Citation: | Australian Journal of Chemistry: an international journal for chemical science, 1985; 38(7):1031-1036 |
| Publisher: | CSIRO Publishing |
| Issue Date: | 1985 |
| ISSN: | 0004-9425 1445-0038 |
| Statement of Responsibility: | AD Abell and RA Massy-Westropp |
| Abstract: | The reaction of methylmagnesium iodide with methyl (1R,3S,5R)-1-(furan- 3′-yl)-5-methyl-2,8-dioxabicyclo[3.2.1]octane-3-carboxylate (2) gives products arising from regioselective carbon-oxygen bond fission and intermolecular transfer of the methyl group of the Grignard reagent to the intermediate oxocarbonium ion, in addition to the usual tertiary alcohol. |
| Rights: | © CSIRO 1985 |
| DOI: | 10.1071/CH9851031 |
| Published version: | http://dx.doi.org/10.1071/ch9851031 |
| Appears in Collections: | Aurora harvest 2 Chemistry publications |
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