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|Title:||Mechanism of acetal cleavage with methylmagnesium iodide|
|Citation:||Australian Journal of Chemistry: an international journal for chemical science, 1985; 38(7):1031-1036|
|AD Abell and RA Massy-Westropp|
|Abstract:||The reaction of methylmagnesium iodide with methyl (1R,3S,5R)-1-(furan- 3′-yl)-5-methyl-2,8-dioxabicyclo[3.2.1]octane-3-carboxylate (2) gives products arising from regioselective carbon-oxygen bond fission and intermolecular transfer of the methyl group of the Grignard reagent to the intermediate oxocarbonium ion, in addition to the usual tertiary alcohol.|
|Rights:||© CSIRO 1985|
|Appears in Collections:||Aurora harvest 2|
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