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https://hdl.handle.net/2440/86027
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Type: | Journal article |
Title: | Photobisdecarbonylation of benzonorbornene-2,3-dione at low temperatures: isolation and characterisation of novel isoindene (2H-indene) dimers |
Author: | Warrener, R.N. Pitt, I.G. Russell, R.A. |
Citation: | Journal of the Chemical Society, Chemical Communications, 1982; 1982(19):1136-1137 |
Publisher: | Royal Society of Chemistry |
Issue Date: | 1982 |
ISSN: | 0022-4936 |
Statement of Responsibility: | Ronald N. Warrener, Ian G. Pitt and Richard A. Russell |
Abstract: | Photolysis of benzonorbornene-2,3-dione in acetone at –60 °C yields a diastereomeric mixture of 1-(indanyl)-1H-indenes considered to arise from [8π+ 8π+ 2 σ]-cyclodimerisation of isoindene: these structures have been confirmed by synthesis, and full stereochemical assignments made following conversion into dihydro-derivatives. |
Rights: | Copyright status unknown |
DOI: | 10.1039/c39820001136 |
Published version: | http://dx.doi.org/10.1039/c39820001136 |
Appears in Collections: | Aurora harvest 7 Chemistry publications |
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