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https://hdl.handle.net/2440/56944
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Type: | Journal article |
Title: | Supramolecular Chemistry of Pyronines B and Y, β-Cyclodextrin and Linked β-Cyclodextrin Dimers |
Other Titles: | Supramolecular Chemistry of Pyronines B and Y, beta-Cyclodextrin and Linked beta-Cyclodextrin Dimers |
Author: | Ngo, H. Clements, P. Easton, C. Pham, D. Lincoln, S. |
Citation: | Australian Journal of Chemistry: an international journal for chemical science, 2010; 63(4):687-692 |
Publisher: | C S I R O Publishing |
Issue Date: | 2010 |
ISSN: | 0004-9425 1445-0038 |
Statement of Responsibility: | Huy T. Ngo, Philip Clements, Christopher J. Easton, Duc-Truc Pham and Stephen F. Lincoln |
Abstract: | <jats:p> The complexation of cationic pyronine B (PB+) and pyronine Y (PY+) by β-cyclodextrin (βCD) and two linked βCD dimers, N,N′-bis((2AS,3AS)-3A-deoxy-β-cyclodextrin-3A-yl)succinamide, 33βCD2suc, and N,N′-bis(6A-deoxy-β-cyclodextrin-6A-yl)succinamide, 66βCD2suc, in aqueous solution has been studied by UV-vis, fluorescence, and 1H NMR spectroscopy. The complexation constants for the 1:1 complexes: βCD.PB+, 33βCD2suc.PB+, 66βCD2suc.PB+, and the analogous PY+ complexes are reported as are the dimerization constants for PB+ and PY+. The modes of complexation, dimerization, and fluorescence quenching are discussed. </jats:p> |
Description: | © CSIRO 2010 |
DOI: | 10.1071/CH09467 |
Grant ID: | ARC |
Published version: | http://dx.doi.org/10.1071/ch09467 |
Appears in Collections: | Aurora harvest 5 Chemistry publications Environment Institute publications |
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