Please use this identifier to cite or link to this item: https://hdl.handle.net/2440/56944
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Type: Journal article
Title: Supramolecular Chemistry of Pyronines B and Y, β-Cyclodextrin and Linked β-Cyclodextrin Dimers
Other Titles: Supramolecular Chemistry of Pyronines B and Y, beta-Cyclodextrin and Linked beta-Cyclodextrin Dimers
Author: Ngo, H.
Clements, P.
Easton, C.
Pham, D.
Lincoln, S.
Citation: Australian Journal of Chemistry: an international journal for chemical science, 2010; 63(4):687-692
Publisher: C S I R O Publishing
Issue Date: 2010
ISSN: 0004-9425
1445-0038
Statement of
Responsibility: 
Huy T. Ngo, Philip Clements, Christopher J. Easton, Duc-Truc Pham and Stephen F. Lincoln
Abstract: <jats:p> The complexation of cationic pyronine B (PB+) and pyronine Y (PY+) by β-cyclodextrin (βCD) and two linked βCD dimers, N,N′-bis((2AS,3AS)-3A-deoxy-β-cyclodextrin-3A-yl)succinamide, 33βCD2suc, and N,N′-bis(6A-deoxy-β-cyclodextrin-6A-yl)succinamide, 66βCD2suc, in aqueous solution has been studied by UV-vis, fluorescence, and 1H NMR spectroscopy. The complexation constants for the 1:1 complexes: βCD.PB+, 33βCD2suc.PB+, 66βCD2suc.PB+, and the analogous PY+ complexes are reported as are the dimerization constants for PB+ and PY+. The modes of complexation, dimerization, and fluorescence quenching are discussed. </jats:p>
Description: © CSIRO 2010
DOI: 10.1071/CH09467
Grant ID: ARC
Published version: http://dx.doi.org/10.1071/ch09467
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