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https://hdl.handle.net/2440/48129
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DC Field | Value | Language |
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dc.contributor.author | Warrener, R. | - |
dc.contributor.author | Margetic, D. | - |
dc.contributor.author | Sun, G. | - |
dc.contributor.author | Russell, R. | - |
dc.date.issued | 2003 | - |
dc.identifier.citation | Australian Journal of Chemistry: an international journal for chemical science, 2003; 56(4):263-267 | - |
dc.identifier.issn | 0004-9425 | - |
dc.identifier.issn | 1445-0038 | - |
dc.identifier.uri | http://hdl.handle.net/2440/48129 | - |
dc.description | © CSIRO 2003 | - |
dc.description.abstract | Succinimide-functionalized N,O-, N,C-, and N,N-bridged benzo[2]polynorbornanes (benzosesquinorbornadienes) are reported for the first time and are prepared by the cycloaddition of either five-membered cyclic 1,3-dienes onto N-substituted benzo-7-azanorbornadienomaleimides or N-substituted isoindoles onto the appropriate norbornadienomaleimides. These products contain an end-fused norbornene (or a 7-substituted relative) and have been designed to act as alkene BLOCKs for the production of nano-scaffolds with up to six addressable sites supplied by each norbornene unit. The N-bridges in these BLOCKs (and their coupled products) allow N-substituent mobility by invertomerization of the sp3 nitrogen whereas the N-substituents on the succinimides are attached to an sp2 nitrogen atom and remain static. Preferred invertomer geometry can be determined using molecular modelling. | - |
dc.description.statementofresponsibility | Ronald N. Warrener, Davor Margetic, Guangxing Sun and Richard A. Russell | - |
dc.language.iso | en | - |
dc.publisher | C S I R O Publishing | - |
dc.source.uri | http://www.publish.csiro.au/nid/51/paper/CH02218.htm | - |
dc.title | Position-Addressable Nano-Scaffolds. I. The Preparation of N O- N C- and N N-Bridged Sesquinorbornadiene Succinimides as Compact Highly Functionalized Addressable Building Blocks | - |
dc.type | Journal article | - |
dc.identifier.doi | 10.1071/CH02218 | - |
pubs.publication-status | Published | - |
Appears in Collections: | Adelaide Graduate Centre publications Aurora harvest |
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