Please use this identifier to cite or link to this item: http://hdl.handle.net/2440/48128
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dc.contributor.authorBos, R.en
dc.contributor.authorBarnett, N.en
dc.contributor.authorDyson, G.en
dc.contributor.authorLim, K.en
dc.contributor.authorRussell, R.en
dc.contributor.authorWatson, S.en
dc.date.issued2004en
dc.identifier.citationAnalytica Chimica Acta, 2004; 502(2):141-147en
dc.identifier.issn0003-2670en
dc.identifier.urihttp://hdl.handle.net/2440/48128-
dc.descriptionCopyright © 2003 Elsevier B.V. All rights reserved.en
dc.description.abstractA simple model peroxyoxalate chemiluminescence system was monitored directly across a range of temperatures (from −80 to +20 °C) using 13C nuclear magnetic resonance spectroscopy. These experiments were made possible by the utilisation of 13C doubly labelled oxalyl chloride, which was reacted with anhydrous hydrogen peroxide in dry tetrahydrofuran. Ab initio quantum calculations were also performed to estimate the 13C nuclear magnetic resonance (NMR) shift of the most commonly postulated key intermediate 1,2-dioxetanedione and this data, in concert with the spectroscopic evidence, confirmed its presence during the reaction.en
dc.description.statementofresponsibilityRichard Bos, Neil W. Barnett, Gail A. Dyson, Kieran F. Lim, Richard A. Russell and Simon P. Watsonen
dc.language.isoenen
dc.publisherElsevier Science BVen
dc.subjectPeroxyoxalate chemiluminescence intermediate; 1,2-Dioxetanedione; Nuclear magnetic resonance spectroscopy; Ab initio quantum calculationsen
dc.titleStudies on the mechanism of the peroxyoxalate chemiluminescence reaction Part 1. Confirmation of 1 2-dioxetanedione as an intermediate using 13C nuclear magnetic resonance spectroscopyen
dc.typeJournal articleen
dc.identifier.rmid0020082810en
dc.identifier.doi10.1016/j.aca.2003.10.014en
dc.identifier.pubid41887-
pubs.library.collectionAdelaide Graduate Centre publicationsen
pubs.verification-statusVerifieden
pubs.publication-statusPublisheden
Appears in Collections:Adelaide Graduate Centre publications

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