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https://hdl.handle.net/2440/4378
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Type: | Journal article |
Title: | Crystal and molecular structures of Ru3(CO)12-n(PMe3)n(n = 1,2) |
Author: | Bruce, M. Skelton, B. White, A. Zaitseva, N. |
Citation: | Australian Journal of Chemistry: an international journal for chemical science, 1997; 50(2):163-168 |
Publisher: | CSIRO Publishing |
Issue Date: | 1997 |
ISSN: | 0004-9425 |
Statement of Responsibility: | Michael I. Bruce, Brian W. Skelton, Allan H. White and Natasha N. Zaitseva |
Abstract: | The crystal and molecular structures of the title compounds are described. Both contain a triangular Ru3 core [average Ru-Ru 2·853 (n = 1), 2·837 Å (n = 2)], with the PMe3 ligands occupying equatorial positions. For n = 2, substantial twisting about the Ru-Ru bonds results in one CO group adopting a semibridging position across the Ru-Ru vector joining a substituted Ru with the Ru(CO)4 fragment. Comparisons are also made with the previously determined n = 3 complex |
Description: | © CSIRO 1997 |
DOI: | 10.1071/C96213 |
Published version: | http://dx.doi.org/10.1071/c96213 |
Appears in Collections: | Aurora harvest 2 Chemistry publications |
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