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Type: Journal article
Title: {D-1,4,7,10 -Tetrakis[(S)-2-hydroxy-propyl-kO]-1,4,7,10-tetraazacyclododecane-k4N}cadmium(II) 4-nitro-phenolate hydrate
Author: Davies, P.
Lincoln, S.
Smith, C.
Taylor, M.
Wainwright, K.
Wallwork, K.
Citation: Acta Crystallographica Section C: Crystal Structure Communications, 2000; C56(1):28-30
Publisher: Blackwell Munksgaard
Issue Date: 2000
ISSN: 0108-2701
Statement of
Philip. J. Davies, Stephen F. Lincoln, Christopher B. Smith, Max R. Taylor, Kevin P. Wainwright and Kia S. Wallwork
Abstract: Crystallization of [Cd(S-thpc12)](ClO4)2·H2O {S-thpc12 is 1,4,7,10-tetrakis[(S)-2-hydroxypropyl]-1,4,7,10-tetraazacyclododecane} in the presence of sodium p-nitrophenolate forms the title complex, [Cd(C20H44N4O4)](C6H 4NO3)(ClO4)·H2O. in which p-nitrophenolate and water separately hydrogen bond to a different pair of cis-related pendant hydroxyl groups which, together with the four N atoms, are themselves hound to CdII in an approximately square antiprismatic arrangement. The diastereoselectivity of the complex-forming process is apparent from the fact that both different disymmetric cations in the asymmetric unit have the same Δ helicity.
Description: Copyright © 2008 International Union of Crystallography
DOI: 10.1107/S0108270199012391
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