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Type: Journal article
Title: An N,P-disubstituted-2-aminophosphaalkene and lithium and potassium complexes of the deprotonated "phosphaamidinate" anion
Author: Boere, Rene T.
Cole, Marcus Lawford
Junk, Peter C.
Masuda, Jason D.
Wolmershauser, Gotthelf
Citation: Chemical Communications, 2004; 22:2564-2565
Publisher: Royal Society of Chemistry
Issue Date: 2004
ISSN: 1359-7345
School/Discipline: School of Chemistry and Physics : Chemistry
Statement of
René T. Boeré, Marcus L. Cole, Peter C. Junk, Jason D. Masuda and Gotthelf Wolmershäuser
Abstract: The reaction of DippPH2 (Dipp = 2,6-iPr2C6H3) with DippNC(p-CH3C6H4)Cl in refluxing xylenes affords DippPC(p-CH3C6H4)N(H)Dipp; deprotonation with alkali metal reagents produces unique lithium and potassium complexes with the ligand in a different geometry to that of the free phosphaamidine.
DOI: 10.1039/b408994d
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Appears in Collections:Chemistry publications

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