Adelaide Research & Scholarship
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https://hdl.handle.net/2440/18001
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| Type: | Journal article |
| Title: | An N,P-disubstituted-2-aminophosphaalkene and lithium and potassium complexes of the deprotonated "phosphaamidinate" anion |
| Author: | Boere, Rene T. Cole, Marcus Lawford Junk, Peter C. Masuda, Jason D. Wolmershauser, Gotthelf |
| Citation: | Chemical Communications, 2004; 22:2564-2565 |
| Publisher: | Royal Society of Chemistry |
| Issue Date: | 2004 |
| ISSN: | 1359-7345 |
| School/Discipline: | School of Chemistry and Physics : Chemistry |
| Statement of Responsibility: | René T. Boeré, Marcus L. Cole, Peter C. Junk, Jason D. Masuda and Gotthelf Wolmershäuser |
| Abstract: | The reaction of DippPH2 (Dipp = 2,6-iPr2C6H3) with DippNC(p-CH3C6H4)Cl in refluxing xylenes affords DippPC(p-CH3C6H4)N(H)Dipp; deprotonation with alkali metal reagents produces unique lithium and potassium complexes with the ligand in a different geometry to that of the free phosphaamidine. |
| DOI: | 10.1039/b408994d |
| Published version: | http://pubs.rsc.org/en/Content/ArticlePDF/2004/CC/B408994D/2004-09-28 |
| Appears in Collections: | Chemistry publications |
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