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Type: Journal article
Title: 11-Hydroxy-3,3-dimethyl-7,12-dioxo-3,4,6,6a,7,12,12a,12b-octahydrobenz[a]anthracen-1-yl acetate
Author: Rozek, T.
Bowie, J.
Skelton, B.
White, A.
Citation: Acta Crystallographica Section C: Crystal Structure Communications, 2003; 59(8):O431-O432
Publisher: Munksgaard Int Publ Ltd
Issue Date: 2003
ISSN: 0108-2701
Statement of
Tomas Rozek, John H. Bowie, Brian W. Skeltonb and Allan H. White
Abstract: The Diels-Alder reaction between 5-hydroxy-1,4-naphthoquinone and 5,5-dimethyl-3-vinyl-1,2-cyclohexadienyl acetate by endo addition gives the title compound, C(22)H(22)O(5), in 68% yield. This racemic diastereoisomer has the opposite regiochemistry to ochromycinone analogues produced previously and may allow access to a new type of anticancer-active saquayamycin analogue.
Description: Copyright © International Union of Crystallography
DOI: 10.1107/S0108270103013374
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