Adelaide Research & Scholarship
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https://hdl.handle.net/2440/17944
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| Type: | Journal article |
| Title: | 11-Hydroxy-3,3-dimethyl-7,12-dioxo-3,4,6,6a,7,12,12a,12b-octahydrobenz[a]anthracen-1-yl acetate |
| Author: | Rozek, T. Bowie, J. Skelton, B. White, A. |
| Citation: | Acta Crystallographica Section C: Crystal Structure Communications, 2003; 59(8):O431-O432 |
| Publisher: | Munksgaard Int Publ Ltd |
| Issue Date: | 2003 |
| ISSN: | 0108-2701 1600-5759 |
| Statement of Responsibility: | Tomas Rozek, John H. Bowie, Brian W. Skeltonb and Allan H. White |
| Abstract: | The Diels-Alder reaction between 5-hydroxy-1,4-naphthoquinone and 5,5-dimethyl-3-vinyl-1,2-cyclohexadienyl acetate by endo addition gives the title compound, C(22)H(22)O(5), in 68% yield. This racemic diastereoisomer has the opposite regiochemistry to ochromycinone analogues produced previously and may allow access to a new type of anticancer-active saquayamycin analogue. |
| Description: | Copyright © International Union of Crystallography |
| DOI: | 10.1107/S0108270103013374 |
| Published version: | http://journals.iucr.org/c/issues/2003/08/00/ta1412/ta1412.pdf |
| Appears in Collections: | Aurora harvest 6 Chemistry publications |
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