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https://hdl.handle.net/2440/104993
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Type: | Journal article |
Title: | Electrochemical film deposition of the zirconium metal-organic framework uio-66 and application in a miniaturized sorbent trap |
Author: | Stassen, I. Styles, M. Van Assche, T. Campagnol, N. Fransaer, J. Denayer, J. Tan, J. Falcaro, P. De Vos, D. Ameloot, R. |
Citation: | Chemistry of Materials, 2015; 27(5):1801-1807 |
Publisher: | American Chemical Society |
Issue Date: | 2015 |
ISSN: | 0897-4756 1520-5002 |
Statement of Responsibility: | Ivo Stassen, Mark Styles, Tom Van Assche, Nicolò Campagnol, Jan Fransaer, Joeri Denayer, Jin-Chong Tan, Paolo Falcaro, Dirk De Vos and Rob Ameloot |
Abstract: | Film deposition is an enabling technology for integration of novel functional materials into real-world practical applications. We report both the anodic and cathodic electrochemical film deposition of UiO-66, a prototype of highly stable, zirconium-based metal−organic frameworks, using zirconium foil as the only metal source. The fundamentally different film formation mechanisms at the cathode and anode result in a significantly different coating adhesion strength, mainly due to the formation of an oxide film serving as a bridging layer at the anode. The patterned deposition capability of the electrochemical method enables the straightforward integration of UiO-66 as a sorbent film in a miniaturized sorbent trap for online analytical sampling and concentration of dilute volatile organic compounds. |
Rights: | © 2015 American Chemical Society |
DOI: | 10.1021/cm504806p |
Published version: | http://dx.doi.org/10.1021/cm504806p |
Appears in Collections: | Aurora harvest 3 Chemical Engineering publications |
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